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Polyvinyl acetal (PVAc) resins, also known as polyvinyl formal
Polyvinyl acetal (PVAc) resins, also known as polyvinyl formal, are derived from the polymerization of vinyl acetal monomers. These resins are known for their excellent adhesive properties, water resistance, and chemical stability. Here is the core description of polyvinyl acetal
- Chemical Resistance: Polyvinyl acetal resins exhibit resistance to a variety of chemicals, making them suitable for applications where exposure to solvents and chemicals is common .
- Adhesive Properties: They have strong adhesion capabilities, particularly to materials such as metals, woods, and leathers, which makes them valuable in the adhesives industry .
- Water Resistance: These resins are known for their resistance to water absorption, which is beneficial for applications where water resistance is crucial .
- Thermal Stability: Polyvinyl acetal resins have a Martin耐热 of 100°C, indicating their ability to withstand moderate heat without significant degradation .
- Physical Properties: They are described as Slightly yellow granules, odourless and tasteless, with a relative density of 1.35 and an elongation rate of 5%-10%, showcasing their physical characteristics .

- Solubility: Polyvinyl acetal resins are soluble in a range of solvents including ethanol, acetone, methyl ethyl ketone, cyclohexanone, ethyl acetate, dichloroethane, benzene, and toluene, which allows for their use in various coating and adhesive formulations .
- Manufacturing Process: The production of polyvinyl acetal involves the reaction of vinyl acetate in a medium such as methanol or ethanol, in the presence of a peroxide initiator like benzoyl peroxide, to form polyvinyl acetate. This is then hydrolyzed in the presence of methanol and sulfuric acid to polyvinyl alcohol, which is subsequently reacted with formaldehyde to form the acetal .
- Applications: Due to their unique properties, polyvinyl acetal resins are used in the production of coatings, adhesives, and as a modifier for other polymers to improve their properties such as water resistance and chemical stability .
In summary, polyvinyl acetal resins are a class of polymers with a broad range of applications due to their chemical resistance, adhesive properties, and thermal stability. Their versatility makes them an important material in the manufacturing of various industrial products.
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